In the title compound, (C5H7N2)6[V10O28]·2H2O, the [V10O28]6− anion is generated by crystallographic inversion symmetry and each of the five vanadium centres adopts a distorted VO6 octahedral geometry. In the crystal structure, a network of N—H⋯O, N—H⋯(O,O) and O—H⋯O hydrogen bonds helps to establish the packing.
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